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a solution of volume 50 cm3 contains 2.0 × 10–3 m fe3 and 1.0 × 10–3 m sn4 in 1 m hcl. this solution is examined by voltammetry at a rotating platinum disk electrode of area 0.30 cm2. at the rotation rate employed, both fe3 and sn4 have mass-transfer coefficients, m, of 10–2 cm/s. (a) calculate the limiting current for the reduction of fe3 under these conditions. (b) a current–potential scan is taken from 1.3 to −0.40 v vs. nhe. make a labeled, quantitatively correct, sketch of the i − e curve that would be obtained. assume that no changes in the bulk concentrations of fe3 and sn4 occur during this scan and that all electrode reactions are nernstian
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