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Sagot :
Answer:
D
Explanation:
Gibb's free energy change(∆G) and Standard electrode potential of electrochemical (Ecell) determine the spontaneity of a reaction.
when ∆G > 0, the reaction is not spontaneous
∆G < 0, the reaction is spontaneous
∆G = 0, the reaction is in equilibrium
when Ecell > 0, the redox reaction is spontaneous
Ecell < 0, the redox reaction is not spontaneous
Ecell = 0, the redox reaction is in equilibrium.
ΔH < 0 contributes to spontaneity.
What is a spontaneous reaction?
- A spontaneous reaction is one that takes place naturally under a certain set of circumstances.
- The general entropy, or chaos, of the system increases in the presence of spontaneous reactions.
How can we determine if a reaction is spontaneous or not?
We can determine it by calculating Gibb's free energy.
How do we calculate Gibb's free energy?
It is calculated by the formula:
ΔG = ΔH - TΔS
- ΔG is the change in Gibb's free energy,
- ΔH is the change in the enthalpy
- ΔS is the change in entropy.
How does ΔG tells if a reaction is spontaneous or not?
- If ∆G > 0, the reaction is not a spontaneous reaction
- ∆G < 0, the reaction is a spontaneous reaction
- ∆G = 0, the reaction is in equilibrium
How does ΔH contribute to the spontaneity of the reaction?
- For a reaction to be a spontaneous reaction, ∆G < 0.
- Consider a reaction, ΔG will be calculated as ΔH - TΔS
- If ∆H < 0 then the ΔH - TΔS will be a lesser value ( more negative) than it would have been when ∆H = 0 or ∆H > 0.
- Therefore ∆H < 0 contributes to spontaneity.
To learn more about ΔH, spontaneous reaction, enthalpy, and entropy here,
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