Answered

Join IDNLearn.com to access a wealth of knowledge and get your questions answered by experts. Discover reliable and timely information on any topic from our network of experienced professionals.

The combustion of 3.795 mg of liquid B, which contains only C, H, and O, with excess oxygen gave 9.708 mg of CO2 and 3.969 mg of H2O. In a molar mass determination, 0.205 g of B vaporized at 1.00atm and 200.0'C and occupied a volume of 89.8 mL. Derive the empirical formula, molar mass, and molecular formula of B and draw three plausible structures

Sagot :

Answer:

Explanation:

9.708 mg of CO₂ will contain 12 x 9.708 / 44 = 2.64 g of C .

3.969 mg of H₂O will contain 2 x 3.969 / 18 = .441 g of H .

mg of O in given liquid B = 3.795 - ( 2.64 + .441 ) = .714 mg

ratio of mg of C , H , O in the compound = 2.64 : .441 : .714

ratio of no of atoms  of C , H , O in the compound

= 2.64 / 12 : .441 /1 : .714 / 16

= .22 : .44 : .0446

= .22 / .22 : .44 / .22 : .044 / .22

= 1 : 2 : .2

1 x 5 : 2 x 5 : .2 x 5

= 5 : 10 : 1

empirical formula of the compound = C₅H₁₀O

Volume of 89.8 mL at 1 .00 atm at 200⁰C

volume of gas at 1 atm and 0⁰C = 89.8 x 273 / 473 mL

= 51.83 mL

51.83 mL weighs .205 g

22400 mL will weigh .205 x 22400 / 51.83 g

= 88.6 g

So molecular weight = 88.6

Let molecular formula be (C₅H₁₀O)ₙ

molecular weight = n ( 5 x 12 + 10 + 16 )

= 86 n

86 n = 88.6

n = 1 approx

So molecular formula is same as empirical formula

C₅H₁₀O is molecular formula .

Your participation is crucial to us. Keep sharing your knowledge and experiences. Let's create a learning environment that is both enjoyable and beneficial. Thank you for choosing IDNLearn.com for your queries. We’re here to provide accurate answers, so visit us again soon.