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In this case, for the given compound and, in agreement with the octet rule, it is possible to realize that the CO is actually C=O as shown below:
CH3 - C - CH2 - CH2 - CH3
||
O
Thus, since the C=O stands for the carbonyl group within the parent chain, we infer this is a ketone and more specifically 2-pentanone as it has five carbon atoms.
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