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Answer:
1. Na2CO3 + 2HCl --> 2NaCl + CO2 + H2O
2. 2NaOH + H2SO4 --> Na2SO4 + H2O
3. CaCO3 + 2HCl --> CaCl2 + CO2 + H2O
4. 4Na + O2 --> 2Na2O