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Can hydrogen Bonds form among hydrogen chloride molecules? Why?
Despite its electronegativity, size of a chlorine atom is larger and hence, the electron density is low. So, HCl does not have hydrogen bonding but, HF,NH3,H2O shows hydrogen bonding.The hydrogen bond does not form because the chlorine atom is too large. Despite chlorine's high electronegativity its big size lowers the negative charge density and it is not enough to attract a hydrogen atom in a stable phase. Nevertheless, there is a small dipole-dipole attraction between adjacent HCL molecules.
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