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Under conditions of very high pressures, the volume would be lower than predicted by the Ideal Gas Law.
According to the kinetic theory of gases, a gas spreads out to fill the volume of the container holding it. Hence a gas does not have a definite volume due to the fact that there is no inter-molecular interaction between gas molecules.
When the gas is subjected to very high pressure, inter-molecular interactions become significant leading to a decrease in the volume of the gas.
Therefore, when subjected to high pressure, the experimental volume would be lower than predicted by the Ideal Gas Law.
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