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#1
Let moles of water can be made be x
[tex]\\ \sf\longmapsto \dfrac{2}{6}=\dfrac{x}{28}[/tex]
[tex]\\ \sf\longmapsto \dfrac{1}{3}=\dfrac{x}{28}[/tex]
[tex]\\ \sf\longmapsto 3x=28[/tex]
[tex]\\ \sf\longmapsto x\approx 9mol[/tex]
#2
Let moles of water can be made be x
[tex]\\ \sf\longmapsto \dfrac{3}{2}=\dfrac{x}{76}[/tex]
[tex]\\ \sf\longmapsto 2x=76(3)=228[/tex]
[tex]\\ \sf\longmapsto x=114mol[/tex]