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Sagot :
Lattice energy is obtained from Hess law of constant heat summation. The lattice energy of MX3 is -6272 kJ/mol.
We have the following information from the question;
Heat of formation (ΔH∘f) = −917 kJ/mol
Heat of sublimation ( ΔHsub) = 131 kJ/mol
Sum of ionization energies of the meta (IE)= (IE1 + 1E2 + IE3) = 4981 kJ/mol
Electron affinity (EA) = −305 kJ/mol
Bond energy of X2 (BE) = 243 kJ/mol
Lattice energy (U) = ?
Using Hess law of constant heat summation;
ΔH∘f = ΔHsub + BE + IE + EA + U
Substituting values;
−917 kJ/mol = 131 kJ/mol + 243 kJ/mol + 4981 kJ/mol + U
U = (−917 kJ/mol) - [ 131 kJ/mol + 243 kJ/mol + 4981 kJ/mol]
U = -6272 kJ/mol
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