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Consider 5.00 mol of liquid water. (a) What volume is occupied by this amount of water? The molar mass of water is 18.0 g/mol. (b) Imagine the molecules to be, on average, uniformly spaced, with each molecule at the center of a sma11 cube. What is the length of an edge of each sma11 cube if adjacent cubes touch but don't overlap? (c) How does this distance compare with the diameter of a molecule?

Sagot :

This question involves the concepts of density, volume, and mass.

(a) The volume occupied by this amount of water is "90 m³".

(b) The length of an edge of each small cube is "83 μm".

(c) The length of the edge of each small cube is "equal" to the diameter of a molecule.

(a)

The volume can be found using the following formula:

[tex]V = \frac{nM}{\rho}[/tex]

where,

V = volume occoupied = ?

n = no. of moles = 5 mol

M = molar mass = 18 g/mol

[tex]\rho[/tex] = density of water = 1 g/m³

Therefore,

[tex]V=\frac{(5\ mol)(18\ g/mol)}{1\ g/m^3}\\\\[/tex]

V = 90 m³

(b)

First, we will find the volume of an individual molecule:

[tex]V_i =\frac{V}{nN_A}[/tex]

where,

[tex]N_A[/tex] = Avogadro's number = 6.02 x 10²³ molecules/mol

Therefore,

[tex]V_i=\frac{90\ m^3}{5\ mol(6.02\ x\ 10^{23}\ molecules/mol)}[/tex]

Vi = 3 x 10⁻²³ m³

This volume can be given as a volume of the sphere:

[tex]V_i=\frac{4}{3}\pi r^3\\\\r=\sqrt[3]{\frac{3(3\ x\ 10^{-23}\ m^3)}{4\pi}}[/tex]

r = 4.15 x 10⁻⁷ m

Diameter = d = 2r = 2(4.15 x 10⁻⁷ m)

d = 8.3 x 10⁻⁷ m = 83 μm

since the cubes are adjacent to each other. Therefore, the diameter will be equal to the edge length.

Edge Length = L = d

L = 8.3 x 10⁻⁷ m = 83 μm

(c)

The edge length is equal to the diameter of the molecule.

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