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condition necessary for thermodynamic equilibrium
For a thermodynamic system to be in equilibrium, all intensive (temperature, pressure) and extensive thermodynamic properties (U, G, A, H, S, etc) must be constants. Hence, the total change in any of those properties (dℑ ) must be zero at equilibrium.
Answer: For a thermodynamic system to be in equilibrium, all intensive (temperature, pressure) and extensive thermodynamic properties (U, G, A, H, S, etc) must be constants. Hence, the total change in any of those properties (dℑ ) must be zero at equilibrium.
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