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In the galvanic or voltaic cell, the standard cell potential is 1.67 V. The standard potential is the difference between the reduction potential of cathode and anode.
An electrochemical cell produces energy by a sponteanous chemical process. A galvanic or voltaic cell produces energy by a sponteanous chemical reaction.
Hence, given the standard reduction potentials;
Sn4+ + 2e- ==> Sn2+ Eº = 0.15 V (anode)
Co3+ + 2e- ==> Co2+ Eº = 1.82 V (cathode)
Eºcell = 1.82 V - 0.15 V = 1.67 V
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