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ANSWER:
Using Snell's law, we can use n1Sinα=n2Sin β where α = Incidence angle, and β=angle of refraction. n1 and n2 are the indices of refraction for water and air.
Sinα=n2/n1 Sinβ For the refracted ray to be along the surface of water, β=90° and therefore Sinβ = 1
So, Sinα=n2/n1= 1/1.33 = 0.7519 => α=sin^-1 (0.7519) = 48.75°.