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The temperature at which a liquid's vapor pressure equals the pressure of the gas above it is known as the boiling point of the liquid. The temperature at which a liquid's vapor pressure equals one atmosphere is considered the liquid's typical boiling point (760).
When the vapor pressure of a liquid equals the pressure of the gas above it, the liquid boils. The temperature at which a liquid will boil decreases with decreasing gas pressure above the liquid.
The Macro Perspective.A liquid's vapor pressure rises as it warms until it reaches the same level as the gas above it. Within the bulk liquid, vaporize liquid (i.e., gas) bubbles form, rise to the surface, burst, and release the gas. (A bubble's internal vapor pressure is sufficient to prevent the bubble from collapsing at boiling temperature.)The liquid's molecules must overcome their forces of attraction in order to create vapor.
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