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Manganese(II) ions are arranged in MnCO3 in an octahedral coordination geometry, giving it a structure similar to that of calcite.
What is octahedral coordination?
The shape of compounds with six atoms or groups of atoms or ligands symmetrically grouped around a central atom, defining the vertices of an octahedron, is described by octahedral molecular geometry, also known as square bipyramidal, in chemistry. The prefix octa refers to the octahedron, which has eight faces. Although octahedral compounds typically have an atom in their center and no links between the ligand atoms, the octahedron is one of the Platonic solids.
To the point group Oh belongs a perfect octahedron. Molybdenum hexacarbonyl Mo(CO)6 and sulfur hexafluoride SF6 are two examples of octahedral chemicals.
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