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For an octahedral complex, the coordination number of the central copper ion is six and it is in the +2 oxidation state.
We know that an octahedral complex is one in which there are six ligands that are attached to the central metal ion. The coordination number has to do with the number of the ligands that could be found around the central metal ion.
Copper is found in the + 2 states when it forms complexes that are octahedral in nature ad the coordination number of the central copper ion in the complex is always six.
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