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When a hydrogen atom is bound to a strongly electronegative atom and is in close proximity to another electronegative atom with a single pair of electrons, an intermolecular force (IMF) known as a hydrogen bond arises. This IMF is a particular sort of dipole-dipole attraction.
A sample's vapor pressure will rise as the temperature rises because the particles will have more energy to dispel the intermolecular forces keeping them in a liquid state.
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