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If an atom Z is replaced by each Ha and Hb in the given structures, two distinct or very different compounds are genrally formed which are diastereomers of one another. As a result, Ha and Hb will produce unique NMR signals in this case.
Stereoisomer that are not the exact mirror reflections of one another are generally designated as Diastereomers. They take place when some of the closely related or equivalent stereocenters of two or generally more stereoisomers of the same molecule do not all have the same configuration, but rather have distinct configurations.
So two diastereomers are usually referred or designated to as epimers when they only differ from each another at a single stereocenter. Due to each stereocenter mostly or generally producing two distinct configurations, there are most frequently twice as many of the stereoisomers as there are the stereocenters.
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