draw the correct products, in either order, for the following oxidative cleavage reaction.

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06-12-2022
Chemistry

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draw the correct products, in either order, for the following oxidative cleavage reaction.

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NomulaHarshidn NomulaHarshidn · Answer 1 · 2022-12-09T02:53:03-05:00

The correct product of the reaction of 1-methylcyclopent-1-ene in basic medium and hydronium ion is 5-oxohexanoic acid.

What is oxidation reaction ?

An oxidation reaction takes place whenever oxygen interacts with a substance or an element. Taking hydrogen out of the reactant species is another way to describe the process of oxidation. The process of oxidation is the loss of electrons by a molecule, an atom, or an ion.

What is cleavage reaction?

Chemical bonds can be split apart through bond cleavage or bond fission. When a molecule is split into two or more pieces, this is generally known as dissociation.

The permanganate ion adds to the double bond in a cis fashion to form a cyclic permanganic ester.

The intermediate cyclic ester undergoes ready hydrolysis to yield a 1,2 diol.

When heated the diols undergo over-oxidation to form ketone or carboxylic acid depending upon the structure of alkene. When atleast one H atom is attached to alkene carbon carboxylic acid is formed. When both alkene carbon is substituted in both ends by alkyl group ketone is the end product.

Oxidative cleavage is a reaction shown by cyclic alkenes in the presence of oxidizing agent, potassium permanganate results in the formation of alcohols and carbonyls.

The double bond present in 1-methylcyclopent-1-ene undergoes oxidative cleavage in the presence of potassium permanganate in basic medium.

Therefore, the correct product of the reaction of 1-methylcyclopent-1-ene in basic medium and hydronium ion is 5-oxohexanoic acid.

Learn more about oxidation reaction from the given link.

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