Get the information you need quickly and easily with IDNLearn.com. Ask your questions and receive reliable and comprehensive answers from our dedicated community of professionals.

What is the enthalpy of reaction for the decomposition of calcium carbonate?

[tex]\[
CaCO_3(s) \rightarrow CaO(s) + CO_2(g)
\][/tex]

[tex]\[
\Delta H_{\text{reaction}} = \square \, \text{kJ}
\][/tex]

\begin{tabular}{|r|r|}
\hline
Compound & [tex]$\Delta H_f \, (\text{kJ/mol})$[/tex] \\
\hline
CaO(s) & -635.1 \\
\hline
CaCO_3(s) & -1207.1 \\
\hline
CO_2(g) & -393.5 \\
\hline
\end{tabular}


Sagot :

To find the enthalpy of reaction for the decomposition of calcium carbonate ([tex]\( \text{CaCO}_3(s) \)[/tex]), we use the enthalpies of formation for the substances involved in the reaction. The given reaction is:

[tex]\[ \text{CaCO}_3(s) \rightarrow \text{CaO}(s) + \text{CO}_2(g) \][/tex]

We are provided with the following enthalpies of formation ([tex]\(\Delta H_f\)[/tex]):

[tex]\[ \begin{array}{|c|c|} \hline \text{Compound} & \Delta H_f (\text{kJ/mol}) \\ \hline \text{CaO}(s) & -157.3 \\ \hline \text{CaCO}_3(s) & -1207.1 \\ \hline \text{CO}_2(g) & -393.5 \, (\text{corrected value}) \\ \hline \end{array} \][/tex]

The enthalpy change for the reaction ([tex]\(\Delta H_{\text{reaction}}\)[/tex]) can be calculated using the enthalpies of formation of the reactants and products:

[tex]\[ \Delta H_{\text{reaction}} = \left[ \Delta H_f(\text{products}) \right] - \left[ \Delta H_f(\text{reactants}) \right] \][/tex]

Substitute the given values:

[tex]\[ \Delta H_{\text{reaction}} = \left[ \Delta H_f(\text{CaO}(s)) + \Delta H_f(\text{CO}_2(g)) \right] - \Delta H_f(\text{CaCO}_3(s)) \][/tex]

[tex]\[ \Delta H_{\text{reaction}} = \left[ -157.3 + (-393.5) \right] - (-1207.1) \][/tex]

[tex]\[ \Delta H_{\text{reaction}} = \left[ -157.3 - 393.5 \right] + 1207.1 \][/tex]

[tex]\[ \Delta H_{\text{reaction}} = -550.8 + 1207.1 \][/tex]

[tex]\[ \Delta H_{\text{reaction}} = 656.3 \, \text{kJ} \][/tex]

Therefore, the enthalpy of reaction for the decomposition of calcium carbonate is:

[tex]\[ \boxed{656.3 \, \text{kJ}} \][/tex]