Connect with knowledgeable individuals and get your questions answered on IDNLearn.com. Ask anything and receive prompt, well-informed answers from our community of experienced experts.
Sagot :
Sure! Let's solve the given two parts systematically:
### Part A: Calculate the Equilibrium Constant [tex]\( K_{\text{eq}} \)[/tex]
For the reaction:
[tex]\[ 2 \text{NOCl} (g) \rightleftharpoons 2 \text{NO} (g) + \text{Cl}_2 (g) \][/tex]
The expression for the equilibrium constant [tex]\( K_{\text{eq}} \)[/tex] is given by:
[tex]\[ K_{\text{eq}} = \frac{[\text{NO}]^2 [\text{Cl}_2]}{[\text{NOCl}]^2} \][/tex]
We're given the following equilibrium concentrations:
- [tex]\([ \text{NO} ] = 0.02 \, \text{M}\)[/tex]
- [tex]\([ \text{Cl}_2] = 0.01 \, \text{M}\)[/tex]
- [tex]\([ \text{NOCl} ] = 0.5 \, \text{M}\)[/tex]
Plugging these values into the equation:
[tex]\[ K_{\text{eq}} = \frac{(0.02)^2 \times 0.01}{(0.5)^2} \][/tex]
Calculating the numerator:
[tex]\[ (0.02)^2 = 0.0004 \][/tex]
[tex]\[ 0.0004 \times 0.01 = 0.000004 \][/tex]
Calculating the denominator:
[tex]\[ (0.5)^2 = 0.25 \][/tex]
So,
[tex]\[ K_{\text{eq}} = \frac{0.000004}{0.25} = 0.000016 \][/tex]
[tex]\[ K_{\text{eq}} = 1.6 \times 10^{-5} \][/tex]
Thus, the value of the equilibrium constant [tex]\( K_{\text{eq}} \)[/tex] is [tex]\( 1.6 \times 10^{-5} \)[/tex].
### Part B: Calculate the pH of a Weak Acid Solution
We're given the concentration of hydrogen ions [tex]\( [\text{H}^+] \)[/tex] as:
[tex]\[ [\text{H}^+] = 2.1 \times 10^{-6} \, \text{M} \][/tex]
The pH of a solution is calculated using the formula:
[tex]\[ \text{pH} = -\log_{10}([\text{H}^+]) \][/tex]
Substituting the given [tex]\( [\text{H}^+] \)[/tex]:
[tex]\[ \text{pH} = -\log_{10}(2.1 \times 10^{-6}) \][/tex]
Calculating the logarithm first:
[tex]\[ \log_{10}(2.1 \times 10^{-6}) = \log_{10}(2.1) + \log_{10}(10^{-6}) \][/tex]
[tex]\[ \log_{10}(2.1) \approx 0.322 \][/tex]
[tex]\[ \log_{10}(10^{-6}) = -6 \][/tex]
Adding these values:
[tex]\[ \log_{10}(2.1 \times 10^{-6}) = 0.322 - 6 = -5.678 \][/tex]
So, the pH is:
[tex]\[ \text{pH} = -(-5.678) = 5.678 \][/tex]
Therefore, the pH of the weak acid solution is approximately 5.68 (more precisely 5.6777807052660805).
### Summary
- The equilibrium constant [tex]\( K_{\text{eq}} \)[/tex] is [tex]\( 1.6 \times 10^{-5} \)[/tex].
- The pH of the weak acid solution is approximately 5.68.
### Part A: Calculate the Equilibrium Constant [tex]\( K_{\text{eq}} \)[/tex]
For the reaction:
[tex]\[ 2 \text{NOCl} (g) \rightleftharpoons 2 \text{NO} (g) + \text{Cl}_2 (g) \][/tex]
The expression for the equilibrium constant [tex]\( K_{\text{eq}} \)[/tex] is given by:
[tex]\[ K_{\text{eq}} = \frac{[\text{NO}]^2 [\text{Cl}_2]}{[\text{NOCl}]^2} \][/tex]
We're given the following equilibrium concentrations:
- [tex]\([ \text{NO} ] = 0.02 \, \text{M}\)[/tex]
- [tex]\([ \text{Cl}_2] = 0.01 \, \text{M}\)[/tex]
- [tex]\([ \text{NOCl} ] = 0.5 \, \text{M}\)[/tex]
Plugging these values into the equation:
[tex]\[ K_{\text{eq}} = \frac{(0.02)^2 \times 0.01}{(0.5)^2} \][/tex]
Calculating the numerator:
[tex]\[ (0.02)^2 = 0.0004 \][/tex]
[tex]\[ 0.0004 \times 0.01 = 0.000004 \][/tex]
Calculating the denominator:
[tex]\[ (0.5)^2 = 0.25 \][/tex]
So,
[tex]\[ K_{\text{eq}} = \frac{0.000004}{0.25} = 0.000016 \][/tex]
[tex]\[ K_{\text{eq}} = 1.6 \times 10^{-5} \][/tex]
Thus, the value of the equilibrium constant [tex]\( K_{\text{eq}} \)[/tex] is [tex]\( 1.6 \times 10^{-5} \)[/tex].
### Part B: Calculate the pH of a Weak Acid Solution
We're given the concentration of hydrogen ions [tex]\( [\text{H}^+] \)[/tex] as:
[tex]\[ [\text{H}^+] = 2.1 \times 10^{-6} \, \text{M} \][/tex]
The pH of a solution is calculated using the formula:
[tex]\[ \text{pH} = -\log_{10}([\text{H}^+]) \][/tex]
Substituting the given [tex]\( [\text{H}^+] \)[/tex]:
[tex]\[ \text{pH} = -\log_{10}(2.1 \times 10^{-6}) \][/tex]
Calculating the logarithm first:
[tex]\[ \log_{10}(2.1 \times 10^{-6}) = \log_{10}(2.1) + \log_{10}(10^{-6}) \][/tex]
[tex]\[ \log_{10}(2.1) \approx 0.322 \][/tex]
[tex]\[ \log_{10}(10^{-6}) = -6 \][/tex]
Adding these values:
[tex]\[ \log_{10}(2.1 \times 10^{-6}) = 0.322 - 6 = -5.678 \][/tex]
So, the pH is:
[tex]\[ \text{pH} = -(-5.678) = 5.678 \][/tex]
Therefore, the pH of the weak acid solution is approximately 5.68 (more precisely 5.6777807052660805).
### Summary
- The equilibrium constant [tex]\( K_{\text{eq}} \)[/tex] is [tex]\( 1.6 \times 10^{-5} \)[/tex].
- The pH of the weak acid solution is approximately 5.68.
We value your participation in this forum. Keep exploring, asking questions, and sharing your insights with the community. Together, we can find the best solutions. Your questions deserve precise answers. Thank you for visiting IDNLearn.com, and see you again soon for more helpful information.