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We emphasize the valence electrons in an atom when discussing atomic properties, as they are most accessible to other atoms.
The valence electrons are the electrons that are present in the outer shell of the atoms. These electrons are free for making bonds with the electrons of other atoms.
Electrons are joined with other electrons to make a compound. These electrons are shared by or gained by other atoms.
Thus, when discussing atomic qualities, we focus on the valence electrons in an atom since they are the most receptive to other atoms.
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